Spectroelectrochemical behaviour of poly (3-octylthiophene): application to electrochromic windows with polyaniline and iridium oxide
Identifieur interne : 000149 ( Main/Exploration ); précédent : 000148; suivant : 000150Spectroelectrochemical behaviour of poly (3-octylthiophene): application to electrochromic windows with polyaniline and iridium oxide
Auteurs : RBID : ISTEX:10800_1994_Article_BF00243332.pdfAbstract
The spectroelectrochemical behaviour of cast poly(3-octylthiophene) (POT) films (0.2 and 0.5 μm) on indium-tin-oxide (ITO) glass electrodes has been investigated in organic media. These thin films exhibit interesting electrochromic properties and their application in electrochromic devices has been examined in liquid (CH3CN + LiClO4 0.3 M) and viscous electrolyte (PEO + CH3CH + LiClO4). Polyaniline (PANI) film appears to be a convenient complementary counter electrode since its transmission maximum corresponds to its oxidized state and that of POT film to its reduced state. Thin films of iridium oxide (IrO2) are also possible counter electrodes, even in acetonitrile, the electrochemical behaviour being mostly capacitive with a low transmission change. However, the best contrast is obtained with the POT/PANI system.
DOI: 10.1007/BF00243332
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Langlois</name><affiliation wicri:level="3"><mods:affiliation>Laboratoire d'Electrochimie Moléculaire, Service des Systèmes et Architectures Moléculaires, Département de Recherche Fondamentale sur la Matière Condensée, Centre d'Etudes Nucléaires de Grenoble, 85X, 38041, Grenoble, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire d'Electrochimie Moléculaire, Service des Systèmes et Architectures Moléculaires, Département de Recherche Fondamentale sur la Matière Condensée, Centre d'Etudes Nucléaires de Grenoble, 85X, 38041, Grenoble</wicri:regionArea><placeName><region type="region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author><author><name>E. Genies</name><affiliation wicri:level="3"><mods:affiliation>Laboratoire d'Electrochimie Moléculaire, Service des Systèmes et Architectures Moléculaires, Département de Recherche Fondamentale sur la Matière Condensée, Centre d'Etudes Nucléaires de Grenoble, 85X, 38041, Grenoble, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire d'Electrochimie Moléculaire, Service des Systèmes et Architectures Moléculaires, Département de Recherche Fondamentale sur la Matière Condensée, Centre d'Etudes Nucléaires de Grenoble, 85X, 38041, Grenoble</wicri:regionArea><placeName><region type="region" nuts="2">Rhône-Alpes</region><settlement type="city">Grenoble</settlement></placeName></affiliation></author></titleStmt><publicationStmt><idno type="RBID">ISTEX:10800_1994_Article_BF00243332.pdf</idno><date when="1994">1994</date><idno type="doi">10.1007/BF00243332</idno><idno type="wicri:Area/Main/Corpus">000D00</idno><idno type="wicri:Area/Main/Curation">000D00</idno><idno type="wicri:Area/Main/Exploration">000149</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="eng">The spectroelectrochemical behaviour of cast poly(3-octylthiophene) (POT) films (0.2 and 0.5 μm) on indium-tin-oxide (ITO) glass electrodes has been investigated in organic media. These thin films exhibit interesting electrochromic properties and their application in electrochromic devices has been examined in liquid (CH3CN + LiClO4 0.3 M) and viscous electrolyte (PEO + CH3CH + LiClO4). Polyaniline (PANI) film appears to be a convenient complementary counter electrode since its transmission maximum corresponds to its oxidized state and that of POT film to its reduced state. Thin films of iridium oxide (IrO2) are also possible counter electrodes, even in acetonitrile, the electrochemical behaviour being mostly capacitive with a low transmission change. However, the best contrast is obtained with the POT/PANI system.</div></front></TEI><mods xsi:schemaLocation="http://www.loc.gov/mods/v3 file:///applis/istex/home/loadistex/home/etc/xsd/mods.xsd" version="3.4" istexId="e0f816b23251a1279f013c64cfd791a7165851c5"><titleInfo lang="eng"><title>Spectroelectrochemical behaviour of poly (3-octylthiophene): application to electrochromic windows with polyaniline and iridium oxide</title></titleInfo><name type="personal"><namePart type="given">M.-N.</namePart><namePart type="family">Collomb-Dunand-Sauthier</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Laboratoire d'Electrochimie Moléculaire, Service des Systèmes et Architectures Moléculaires, Département de Recherche Fondamentale sur la Matière Condensée, Centre d'Etudes Nucléaires de Grenoble, 85X, 38041, Grenoble, France</affiliation></name><name type="personal"><namePart type="given">S.</namePart><namePart type="family">Langlois</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Laboratoire d'Electrochimie Moléculaire, Service des Systèmes et Architectures Moléculaires, Département de Recherche Fondamentale sur la Matière Condensée, Centre d'Etudes Nucléaires de Grenoble, 85X, 38041, Grenoble, France</affiliation></name><name type="personal"><namePart type="given">E.</namePart><namePart type="family">Genies</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Laboratoire d'Electrochimie Moléculaire, Service des Systèmes et Architectures Moléculaires, Département de Recherche Fondamentale sur la Matière Condensée, Centre d'Etudes Nucléaires de Grenoble, 85X, 38041, Grenoble, France</affiliation></name><typeOfResource>text</typeOfResource><genre>Papers</genre><genre>Original Paper</genre><originInfo><publisher>Kluwer Academic Publishers, Dordrecht</publisher><dateCreated encoding="w3cdtf">1993-02-10</dateCreated><dateValid encoding="w3cdtf">2004-07-31</dateValid><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="eng">The spectroelectrochemical behaviour of cast poly(3-octylthiophene) (POT) films (0.2 and 0.5 μm) on indium-tin-oxide (ITO) glass electrodes has been investigated in organic media. These thin films exhibit interesting electrochromic properties and their application in electrochromic devices has been examined in liquid (CH3CN + LiClO4 0.3 M) and viscous electrolyte (PEO + CH3CH + LiClO4). Polyaniline (PANI) film appears to be a convenient complementary counter electrode since its transmission maximum corresponds to its oxidized state and that of POT film to its reduced state. Thin films of iridium oxide (IrO2) are also possible counter electrodes, even in acetonitrile, the electrochemical behaviour being mostly capacitive with a low transmission change. However, the best contrast is obtained with the POT/PANI system.</abstract><relatedItem type="series"><titleInfo type="abbreviated"><title>J Appl Electrochem</title></titleInfo><titleInfo><title>Journal of Applied Electrochemistry</title><partNumber>Year: 1994</partNumber><partNumber>Volume: 24</partNumber><partNumber>Number: 1</partNumber></titleInfo><genre>Archive Journal</genre><originInfo><dateIssued encoding="w3cdtf">1994-01-01</dateIssued><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><subject usage="primary"><topic>Chemistry</topic><topic>Physical Chemistry</topic><topic>Industrial Chemistry/Chemical Engineering</topic></subject><identifier type="issn">0021-891X</identifier><identifier type="issn">Electronic: 1572-8838</identifier><identifier type="matrixNumber">10800</identifier><identifier type="local">IssueArticleCount: 15</identifier><recordInfo><recordOrigin>Chapman & Hall, 1994</recordOrigin></recordInfo></relatedItem><identifier type="doi">10.1007/BF00243332</identifier><identifier type="matrixNumber">Art11</identifier><identifier type="local">BF00243332</identifier><accessCondition type="use and reproduction">MetadataGrant: OpenAccess</accessCondition><accessCondition type="use and reproduction">AbstractGrant: OpenAccess</accessCondition><accessCondition type="restriction on access">BodyPDFGrant: Restricted</accessCondition><accessCondition type="restriction on access">BodyHTMLGrant: Restricted</accessCondition><accessCondition type="restriction on access">BibliographyGrant: Restricted</accessCondition><accessCondition type="restriction on access">ESMGrant: Restricted</accessCondition><part><extent unit="pages"><start>72</start><end>77</end></extent></part><recordInfo><recordOrigin>Chapman & Hall, 1994</recordOrigin><recordIdentifier>10800_1994_Article_BF00243332.pdf</recordIdentifier></recordInfo></mods></record>Pour manipuler ce document sous Unix (Dilib)
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